Hanna Instruments offers a wide variety of ORP electrodes that are designed for many different applications. The type of material used for the sensing pin, type of glass used for body material, type of junction, type of reference and electrolyte used are just some of the design considerations.
The HI3131B uses a platinum pin, glass body, single ceramic junction and is refillable with 3.5M KCl + AgCl.
Platinum Sensing Pin
The HI3131B ORP sensor is made with platinum. An ORP sensor must be chemically inert; it cannot be oxidized or reduced itself. It must also have the proper surface characteristics to promote rapid electron exchange, a property known as high exchange current density. Two noble metals have proven to work well for this purpose: pure platinum and pure gold are both used in the construction of ORP sensors. The platinum sensor is often preferred because it is mechanically simpler and safer to produce. Platinum can be welded to glass and has the same thermal coefficient. The platinum sensor signal is carried through the electrode body, and together with the reference signal is conducted to the measurement meter.
The glass body is ideal for laboratory use. The glass is resistant to many harsh chemicals and is easily cleaned. The glass body also allows for a fast transfer of heat to the internal reference electrolyte. The mV generated by the reference cell is temperature dependent. The faster the equilibrium the steadier the reference potential.
Single Ceramic Junction
The outer junction of an electrode, also known as a salt bridge, is necessary component of the electrical circuit. The movement of ions must flow through the junction for a steady reading. The outer reference has a single ceramic frit. The ceramic is a porous material that is easily fused with the glass body and has a similar expansion coefficient. A single ceramic junction has a flow rate of 15-20 μL/hour. Other junction types are available with higher flow rates and made with different materials.
The HI3131B is a refillable probe. Since it is a single junction ORP electrode the fill solution is the HI7071 3.5M KCl + AgCl. If using a refillable ORP electrode, the fill cap should be removed prior to measurement. Removing the cap creates positive head pressure in the reference cell allowing for higher flow rate of electrolyte through the outer junction. A higher flow rate will result in a faster and more stable reading.
The HI3131B uses a BNC connector. This type of connector is universal in that it can be used on any pH meter that has the female BNC probe input. Other type of connectors include DIN, screw type, T-type, and 3.5mm to name a few. These types of connectors tend to be proprietary for a particular type of meter and are not interchangeable.
ORP Sensing Type Platinum Measurement Range ORP: ±2000 mV Reference Cell Type single, Ag/AgCl Junction Type/Flow Rate ceramic, single / 15-20 μL/h Refill Electrolyte 3.5M KCl + AgCl Body Material glass Tip / Shape platinum pin Matching Pin no Max. Pressure 0.1 bar Temperature Operating Range -5 to 70°C (23 to 158°F) Body Length/Overall Length 150 mm / 205.5 mm Temperature Sensor no Outer Diameter 12 mm Cable coaxial; 1 m (3.3’) Connector Type BNC Amplifier no Recommended Use general purpose, laboratory general purpose, ORP titrations